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The applicability of the Principle of Corresponding States (PCS) for thenoble fluids is discussed. We give the thermodynamic evidences for thedimerization of the liquid phase in heavy noble gases like argon, krypton etc.which manifest itself in deviation from the PCS. The behavior of therectilinear diameter of the entropy and the density is analyzed. It is shownthat these characteristics are very sensitive to the dimerization process whichtakes place in the liquid phase of heavy noble gases.

Is the thermodynamic behavior of the noble fluids consistent with the Principle of Corresponding States?