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Ro-vibrational spectra of the $\nu_3$ and $\nu_6$ bands of chloromethane($\mathrm{CH_3Cl}$) were recorded in the 650--1130 $\mathrm{cm}^{-1}$ rangeusing a Fourier transform spectrometer at the AILES beamline of the SOLEILsynchrotron facility. Two isotopologues ($\mathrm{CH_3^{35}Cl}$ and$\mathrm{CH_3^{37}Cl}$) have been analyzed with the tensorial formalismdeveloped in Dijon and a total of 6753 lines were assigned. We derived 23tensorial parameters for the lines positions (4 for the ground state, 6 for$\nu_3$, and 13 for $\nu_6$), and 7 for the lines intensities (4 for $\nu_3$, 3for $\nu_6$). From those parameters and self-broadening coefficients found inthe literature, we simulated spectra of both isotopologues. The derivedparameters were converted in the Watson formalism to be compared with aprevious study. Using these results, we set up a new database of calculatedchloromethane spectral lines (ChMeCaSDa).

High-resolution far-infrared spectroscopy and analysis of the $\nu$3 and $\nu$6 bands of chloromethane