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We propose the phase diagram of a new pseudo-ternary compound,CoMnGe_{1-x}Sn_{x}, in the range x less than or equal to 0.1. Our phase diagramis a result of magnetic and calometric measurements. We demonstrate theappearance of a hysteretic magnetostructural phase transition in the rangex=0.04 to x=0.055, similar to that observed in CoMnGe under hydrostaticpressure. From magnetisation measurements, we show that the isothermal entropychange associated with the magnetostructural transition can be as high as 4.5J/(K kg) in a field of 1 Tesla. However, the large thermal hysteresis in thistransition (~20 K) will limit its straightforward use in a magnetocaloricdevice.

Phase diagram and magnetocaloric effect of CoMnGe_{1-x}Sn_{x} alloys