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Crystallographic data and thermoelectric properties (from 240 K up to 380 K)of Yb3Co4Ge13, Yb3Co4Sn13 compounds and Yb2CeCo4Ge13 and Yb2.3La0.7Co4Ge13solid solutions are reported. The Seebeck coefficients, electric resistance andthermal conductivity increase monotonically with increasing temperature from240 to 380 K for all the compounds. The Seebeck coefficient is S = 14 - 27 \muV//K for Yb3Co4Sn13, and S = -21 -- -12 \mu V/K for Yb3Co4Ge13. Thesubstitution of Yb for cerium or lanthanum in Yb3Co4Ge13 shifts the Seeebeckcoefficient to positive values. The Yb3Co4Sn13 has a maximal ZT parameter fromavailable Pr3Rh4Sn13-type compounds. The ZT parameter of Yb3Co4Sn13 compoundincreases from 0.006 up to 0.017 with increasing temperature from 240 K to 380K.

Thermoelectric properties of Pr3Rh4Sn13-type Yb3Co4Ge13 and Yb3Co4Sn13 compounds