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Dimethyl carbonate (DMC) synthesis from methanol and CO2was investigated using ionic liquids (ILs) as catalysts. ILs based on 1-alkyl-3-methyl imidazolium and N-alkylpyridine cations and [Cl−], [BF4−], [PF6−], [Tf2N−] anions were used in this study. Selectivity in DMC increased in the anion order: [Tf2N−]

Chemical Conversion of CO2: Evaluation of Different Ionic Liquids as Catalysts in Dimethyl Carbonate Synthesis