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Hot salt stress corrosion cracking in Ti 6246 alloy has been investigated toelucidate the chemical mechanisms that occur. Cracking was found to initiatebeneath salt particles in the presence of oxidation. The observed transgranularfracture was suspected to be due to hydrogen charging; XRD and high-resolutiontransmission electron microscopy detected the presence of hydrides that wereprecipitated on cooling. SEM-EDS showed oxygen enrichment near salt particles,alongside chlorine and sodium. Aluminium and zirconium were also involved inthe oxidation reactions. The role of intermediate corrosion products such asNa2TiO3, Al2O3, ZrO2, TiCl2 and TiH are discussed.

The mechanisms of hot salt stress corrosion cracking in titanium alloy Ti-6Al-2Sn-4Zr-6Mo