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Water condensation was studied on silanized (superhydrophobic) andfluorinated (superoleophobic) micro-rough aluminum surfaces of the sametopography. Condensation on superhydrophobic surfaces occurred via film-wisemechanism, whereas on superoleophobic surfaces it was drop-wise. The differencein the pathways of condensation was attributed to the various energy barriersseparating the Cassie and Wenzel wetting states on the investigated surfaces.The higher barriers inherent for superoleophobic surfaces promoted thedrop-wise condensation. Triple-stage kinetics of growth of droplets condensedon superoleophobic surfaces is reported and discussed.

Drop-Wise and Film-Wise Water Condensation Processes Occurring on Metallic Micro-Scaled Surfaces