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Recently, An electron-doped 12442-type iron-based superconductorBaTh$_2$Fe$_4$As$_4$(N$_{0.7}$O$_{0.3}$)$_2$ has been successfully synthesizedwith high-temperature solid-state reactions on basis of a structural design.The inter-block-layer charge transfer between the constituent units of"BaFe$_2$As$_2$" and "ThFeAsN$_{0.7}$O$_{0.3}$" was found to be essential tostabilize the target compound. Dominant electron-type conduction and bulksuperconducting transition at ~22 K were demonstrated.

BaTh$_2$Fe$_4$As$_4$(N$_{0.7}$O$_{0.3}$)$_2$: An Iron-Based Superconductor Stabilized by Inter-Block-Layer Charge Transfer