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HighlightsHierarchically porous Fe–Co/N-doped carbon/rGO (Fe–Co/NC/rGO) composites were successfully prepared. Macropores, mesopores, and micropores coexisted in the composites.    Hierarchically porous Fe–Co/NC/rGO showed effective bandwidth of 9.29 GHz.Electronic supplementary material  The online version of this article (10.1007/s40820-019-0307-8) contains supplementary material, which is available to authorized users.

Rational Construction of Hierarchically Porous Fe–Co/N-Doped Carbon/rGO Composites for Broadband Microwave Absorption