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HighlightsS-doped porous carbons (SCs) derived from conjugated microporous polymers were synthesized for Na-ion batteries.    The SCs exhibited a high capacity of 440 mAh g −1  at 50 mA g −1  and excellent cycling performance.    Ex situ X-ray photoelectron spectroscopy was used to investigate the electrochemical reaction mechanism of the SCs.Electronic supplementary material  The online version of this article (10.1007/s40820-019-0291-z) contains supplementary material, which is available to authorized users.

High-Performance Na-Ion Storage of S-Doped Porous Carbon Derived from Conjugated Microporous Polymers