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Euglobal-IIIa ( 1 ), a novel acylphloroglucinol-sesquiterpene derivative, and a known analogue, have been isolated from leaves of  Eucalyptus robusta . The structures was elucidated by extensive spectroscopic data and by comparison with data reported in literature, while the absolute configuration of  1  was determined by the X-ray diffraction analysis. Compound  1  exhibited comparable cytotoxicity with that of cisplatin against five human cancer cell lines HL-60, SMMC-7721, A-549, MCF-7, and SW480 with IC 50  values of 15.7, 15.5, 17.6, 14.3, and 21.8 µM, respectively.Electronic Supplementary Material  Supplementary material is available for this article at 10.1007/s13659-011-0021-9 and is accessible for authorized users.

Euglobal-IIIa, a novel acylphloroglucinol-sesquiterpene derivative from Eucalyptus robusta: absolute structure and cytotoxicity