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Under considerations in the current study are reactions of the type [Mn(LOH)(2)](2+) → [Mn(LO)](+) + LOH(2)(+), where the ligand LOH represents water or/and methanol. Preferential proton transfer reactions and loss of any ligand fragments are discussed in the light of ligand polarizability, dipole moment, dissociation energy, proton affinity, differences in ligand-ion ionization energy, and ion radii. The results indicate the proton affinity and dissociation energy of the O-H bond are more important for the overall proton transfer reaction than differences in the first ionization energy of the ligand and the second ionization energy of the metal ion.

Proton Transfer Reactions for Methanol and Water Containing Manganese Ion Complexes