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Large dynamic index measurement range (n = 1 to n = 1.7) using surfaceplasmon resonance (SPR) shifts is demonstrated with a ZnSe prism at 632.8 nm,limited by the available high index liquid hosts. In contrast to borosilicatebased SPR measurements where angular limitations restrict solvent use to waterand requires considerable care dealing with Fresnel reflections, the ZnSeapproach allows SPR spectroscopies to be applied to a varied range of solventsAn uncertainty in angular resolution between 1.5 and 6 deg, depending on thesolvent and SPR angle, was estimated. The refractive index change for a givenglucose concentration in water was measured to be n = (0.114 to 0.007) perprecentage C6H12O6 conc. Given the transmission properties of ZnSe theprocesses can be readily extended into the mid infrared.

Large dynamic range SPR measurements in the visible using a ZnSe prism