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Gas-condensate reservoirs experience significant productivity losses as reservoir pressure drops below the dew point due to condensate accumulation and water blocking and the subsequent reduction in gas relative permeability. One potential way to overcome this problem is to alter reservoir wettability to gas-wetting to reduce condensate accumulation and water blocking in the near wellbore and maintain high productivity. The major goal of this work was to study the mobility of the gas and liquid phase (both water and oil) before and after wettability alteration from strong liquid-wetting to intermediate gas-wetting. For this purpose, in addition to relative permeability measurements, we also conducted various other tests to demonstrate that liquid mobility can be improved significantly due to wettability alteration. As wettability modifiers, fluorinated polymers are capable of delivering a good level of oil and water repellency to the rock surface, making it intermediate gas-wet and alleviating such liquid blockage under high temperature. The contact angle analyses, capillary rise, flow tests, and imbibition spontaneous tests were used to estimate the effect of treatments on wettability. Experimental results demonstrated that the fluorinated polymers can alter the wettability of cores from strong liquid-wetting to gas-wetting, which could decrease the amount of water invaded and resided in the gas formation. Core flood test results demonstrated that the relative permeabilities of both the gas and the liquid phases were increased significantly after the wettability alteration to preferential gas-wetness. The residual liquid saturation was decreased, and the gas production was enhanced greatly due to the wettability alteration. These results imply that gas well deliverability may increase substantially when wettability is altered to intermediate gas-wetting. Efficiency in the extraction of natural gas is important to improve the productivity of gas-condensate reservoirs where liquid accumulates, which is beneficial for the economic and environmental considerations of the oil and gas industry.

Wettability alteration to intermediate gas-wetting in low-permeability gas-condensate reservoirs