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The rare earth oxides can be used as tracers forthe identification of polymer materials. This study focusedon the detection of these particles and their effects on themechanical and thermal properties of polypropylene (PP).A new method was carried out to increase the sortingselectivity of PP during end of life recycling process and toimprove the efficiency of sorting and its high speed identification.The tests were realized in a test system devicewhich allows the collection of static measurements of thesamples spectrum through the use of energy dispersiveX-ray fluorescence technology. Five of the seven tracerstested are clearly visible and distinguishable from thebackground sample by their Ka1 energy line at concentrationlevels of 0.1 and 0.145 wt%. For the two remainingtracers, their Ka1 energy lines come out at the same domainof energy as the source. Dispersion of rare earth oxides at0.1 and 1 wt% do not have a significant impact on thecrystallization and melting temperature as well as on thetemperature of maximum decomposition rate. The additionof 1 wt% of rare earth oxides leads to a slight increase ofthe flexural modulus, whereas the addition of 0.1 and 1wt% causes a decrease of the elongation at break. SEMimages show a homogenous dispersion of tracers in the PPmatrix.International audienceAbstract The rare earth oxides can be used as tracers forthe identification of polymer materials. This study focusedon the detection of these particles and their effects on themechanical and thermal properties of polypropylene (PP).A new method was carried out to increase the sortingselectivity of PP during end of life recycling process and toimprove the efficiency of sorting and its high speed identification.The tests were realized in a test system devicewhich allows the collection of static measurements of thesamples spectrum through the use of energy dispersiveX-ray fluorescence technology. Five of the seven tracerstested are clearly visible and distinguishable from thebackground sample by their Ka1 energy line at concentrationlevels of 0.1 and 0.145 wt%. For the two remainingtracers, their Ka1 energy lines come out at the same domainof energy as the source. Dispersion of rare earth oxides at0.1 and 1 wt% do not have a significant impact on thecrystallization and melting temperature as well as on thetemperature of maximum decomposition rate. The additionof 1 wt% of rare earth oxides leads to a slight increase ofthe flexural modulus, whereas the addition of 0.1 and 1wt% causes a decrease of the elongation at break. SEMimages show a homogenous dispersion of tracers in the PPmatrix

Elaboration and Characterization of Traced Polypropylene with Rare Earth Oxides for Automatic Identification and Sorting of End-of-Life Plastics