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The distributions of calcium and magnesium between silicon and CaO-MgO-SiO slags have been determined in the present study at 1873 K (1600 °C). The distribution equilibria were used to estimate the activities of the slag components in the binary CaO-SiO and MgO-SiO systems. These activities were used to determine the Henrian activity coefficients of calcium and magnesium in liquid silicon at 1873 K (1600 °C). The distribution equilibria were also used to estimate the activity of SiO in the ternary CaO-MgO-SiO system. Finally, the activities of CaO and MgO were estimated in the ternary CaO-MgO-SiO system using the determined Henrian activity coefficients in liquid silicon together with the distribution equilibria and the estimated activities of SiO.

Thermodynamic Activities and Distributions of Calcium and Magnesium Between Silicon and CaO-MgO-SiO2 Slags at 1873 K (1600 °C)