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In the present work, the effect of different nanofiller (BaTiO3, CeO2, Er2O3or TiO2) on blend solid polymer electrolyte comprising of PEO and PVC complexedwith bulky LiPF6 have been explored. The XRD analysis confirms the polymernanocomposite formation. FTIR provides evidence of interaction among thefunctional groups of the polymer with the ions and the nanofiller in terms ofshifting and changing peak profile. The highest ionic conductivity is ~2.3x10-5S cm-1 with a wide electrochemical stability window of ~3.5 V for 10 wt. %Er2O3. The real and imaginary part of dielectric permittivity follows theidentical trend of the decreasing value with increase in the frequency. Theparticle size and the dielectric constant shows an abnormal trend withdifferent nanofiller. The ac conductivity follows the universal power law. Aneffective mechanism has been proposed to understand the nanofiller interactionwith cation coordinated polymer in the investigated system.

Effect of Variation of Different Nano filler on Structural, Electrical, Dielectric and Transport Properties of Blend Polymer Nanocomposites