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La2Zr2O7 (LZO) formation of bulk powders and of films by Chemical SolutionDeposition (CSD) process have been studied using propionates. The treatmentinvolved a one step cycle in the reducing forming gas (Ar-5%H2) to becompatible with Ni-5at%W RABITS. Large amount of residual carbon was found inLZO powders formed in these conditions (10 wt %). The volume fraction of thecube texture in LZO films on Ni-5at%w RABITS was found to be a function of thespeed of the gas flown above sample. This phenomenon is discussed inconsidering the C deposited from the carbon-containing gases emitted during thepyrolysis of the precursor. Using proper conditions (950 ^\circC and the speedof gas of 6.8\times10^{-2} m/s), LZO films with good surface crystallinitycould be obtained on Ni-5at%W RABITS as demonstrated by X-ray diffraction,electron backscattered diffraction and RHEED. The existence of residual carbonin oxide films is a common question to films deposited by CSD processes underreducing condition.

Deposition of La2Zr2O7 Film by Chemical Solution Deposition