English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

The photoredox ability of a hexarhenium(III) cluster, [Re-6(mu (3)-S)(8)Cl-6](4-), in acetonitrile was examined on the basis of the emission quenching experiments of the cluster by a series of neutral organic electron acceptors (A). The photoinduced electron transfer quenching rate constants and the relevant activation parameters demonstrated that the hexarhenium(III) cluster acted as a useful photoredox sensitizer towards various A and the system gave a high charge separation yield owing to electrostatic repulsion between the product ions: [Re-6(mu (3)-S)(8)Cl-6](3-) and A (-). These results were proved explicitly by nanosecond transient absorption spectroscopy

Photoinduced Electron Transfer Reactions of Hexarhenium(III) Cluster: Oxidative Quenching of [Re6S8Cl6]4− Emission by Electron Acceptors