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pathways. he application of physical chemistry to problems in understanding the reactivity of organic substances is one of the significant events in the development of main group molecular chemistry. Over the last 50 years, the contemporary mechanistic model for structurereactivity relationships has emerged from the seemingly endless and encyclopedic inventory of these ideas into introductory instruction has been embraced but not necessarily melded. In this article, the argument is made that the existing richness of physical organic chemistry provides an overlooked

Progress in Practice: Organic Chemistry in the Introductory Course II. The Advantages of Physical Organic Chemistry