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Using the pure spinor master action for 10D super-Yang-Mills in the gauge$b_{0}V = Q\Xi$, tree-level scattering amplitudes are calculated through theperturbiner method, and shown to match those obtained from pure spinor CFTtechniques. We find kinematic numerators made of nested $b$-ghost operators,and show that the Siegel gauge condition $b_{0}V = 0$ gives rise tocolor-kinematics duality satisfying numerators whose Jacobi identity followsfrom the Jacobi identity of a kinematic algebra.

10D Super-Yang-Mills Scattering Amplitudes From Its Pure Spinor Action