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We study the asymptotic behaviour of the so-called effectiveness factor ηε of a nonlinear diffusion equation that occurs on the boundary of periodically distributed inclusions (or particles) in an ε-periodic medium. Here, ε is a small parameter related to the characteristic size of the inclusions, which, in the homogenization process, will tend to 0. The inclusions are modeled as homothecy of a fixed pellet T, rescaled by a factor r(ε). We study the cases in which r(ε) = O(εα), known as big holes, for α = 1, as well as non-critical small holes, for $$1 > \alpha \frac{n}{{n - 2}}$$1>αnn−2. We will prove the existence of some convex shapes which maximize the effectiveness of the homogenized problem. In particular, we deduce that for small holes the sphere is the domain of highest effectiveness.

The Effectiveness Factor of Reaction-Diffusion Equations: Homogenization and Existence of Optimal Pellet Shapes