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Bimetallic clusters containing gold in conjunction with Group 8 metals have been intensively studied as it is proposed that these compounds may find uses as catalysts or materials (or as precursors to catalysts/materials). These types of compounds are very difficult to characterize by the mass spectrometric techniques traditionally used to analyse transition metal clusters. In this paper we report a derivatization method employing electrospray ionization mass spectrometry that is reliable and informative for these types of compounds.

Electrospray mass spectrometric characterization of bimetallic group 8 — Gold clusters