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The luminescence of Pb(OH) 3 − in deaerated aqueous solution is quenched by hydroxide withk = 1.87 × 105 Lmol−1 s−1. It is suggested that this quenching is associated with an electron transfer from hydroxide to Pb(OH) 3 − in its3P1 sp-excited state. This assumption is supported by the photochemical behaviour of Pb(OH) 3 − which is photoreduced to metallic lead. The efficiency of the photolysis increase with hydroxide concentration

journal of chemical sciences

Photophysics and photochemistry of main group metals with an s2 electron configuration. Luminescence quenching and photoreduction of trihydroxoplumbate (II) by hydroxide