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O(2p)-metal (d) charge-transfer satellites in core level spectra of 3d° metal ions in CaO, Sc2O3, TiO2 and V2O5 and 4d° ions in SrO, Y2O3, ZrO2 and Nb2O5 have been reported. A systematic increase in the satellite separation is noticed going from CaO to V2O5 and from SrO to Nb2O5.

Charge-transfer satellites in the x-ray photoelectron spectra of 3d° and 4d° metal oxides