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The chiral dirhodium(II) carboxamidates are a unique class of chiral catalysts useful for asymmetric inter- and intramolecular cyclopropanation, cyclopropenation and C-H insertion reactions with excellent enantioselectivities. The broad applications of these catalysts in organic syntheses are briefly reviewed.

An overview on the applications of ‘Doyle catalysts’ in asymmetric cyclopropanation, cyclopropenation and C-H insertion reactions