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In this 2nd chapter of the book Quantum Mechanical Prediction ofThermochemical Data" (ed. Jerzy Cioslowski, Kluwer, 2001; ISBN 0-7923-7077-5),we review the nonempirical computational thermochemistry methods W1 and W2theory and their variants. The chapter is made available online following achange in publisher E-print policy.

W1 and W2 Theories, and Their Variants: Thermochemistry in the kJ/mol Accuracy Range