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We derive an explict bias dependent expression for electron transfer reactionrate from a solvated redox to a electrode through a bridged molecule ofarbitrary length. The interaction of the solvated redox with the solvent ismodelled as a classical harmonic oscillator bath. The effect of competingprocess, namely resonance tunneling between redox and bridge and the solvationof the redox is investigated. Plots were produced for the case of 5 atombridge. Our analysis shows that for certain suitable value of nearest-neighbourcoupling, it is possible to block electron transfer in certain intermediatevoltage regime

Electron Transfer rate between a electrode and a bridged redox