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A current series of papers on barrier-controlled and trapping processes insolids and/or at solid surfaces have laid down the emphasis onto describing thestatistical event by means of the barrier currents method due to Bardeen andChristov. The present study centered on photodesorption andphotoelectrification is the fourth of an arXiv series which also included rapidstatistical approaches to nucleation, diffusion and drift currents in state ofthe art materials. We presently extend our arguments to spherical square andoscillatory wells to deal with the photoprocesses.

Statistical transfer rates associated with higher-symmetry  potential-energy wells in solids: Application to photoinduced desorption and  electrification