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DNA plays a special role in polymer science not just because of the highlyselective recognition of complementary single DNA strands but also becausebacteria can express DNA chains that are very long yet perfectly monodisperse.The latter reason makes long DNA molecules widely used as model systems inpolymer science. Here, we report the unusual self-assembly that takes place insystems of colloids coated with very long double-stranded DNA. In particular,we find that colloids coated with such long DNA can assemble into uniquefloating crystalline monolayers. Floating colloidal structures have potentiallyinteresting applications as such ordered structures can be assembled in onelocation and then deposited somewhere else. This would open the way to theassembly of multi-component, layered colloidal crystals.

Colloidal Flying Carpets