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This study focuses on the automatic generation by the software EXGAS ofkinetic models for the oxidation of large methyl esters using a single set ofkinetic parameters. The obtained models allow to well reproduce the oxidationof n-decane / methyl palmitate mixture in a jet-stirred reactor. This paperalso presents the construction and a comparison of models for methyl estersfrom C7 up to C17 in terms f conversion in a jet-stirred reactor and ofignition delay time in a shock tube. This comparison study showed that methylesters larger than methyl octanoate behave similarly and have very closereactivities.

Modeling Study of the Low-Temperature Oxidation of Large Methyl Esters