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In the context of the search for gasoline surrogates for kinetic modelingpurpose, this paper describes a new model for the low-temperature auto-ignitionof n-heptane/iso-octane/hexene/toluene blends for the different linear isomersof hexene. The model simulates satisfactory experimental results obtained in arapid compression machine for temperatures ranging from 650 to 850 K in thecase of binary and ternary mixtures including iso octane, 1-hexene and toluene.Predictive simulations have also been performed for the autoignition of nheptane/iso octane/hexene/toluene quaternary mixtures: the predicted reactivityis close to that of pure iso octane with a retarding effect when going from 1-to 3-alkene.

Detailed kinetic models for the low-temperature auto ignition of gasoline surrogates