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In this letter we report the first room temperature gravimetric measurementsof hydrogen absorption in nanoscale titanium-benzene complexes formed by laserablation in a benzene atmosphere in a UHV chamber. We are able to obtain a 6%by weight absorption as predicted by recent density functional theory basedcalculations under the conditions of low benzene pressure (35 milli-torr) andfor sub-monolayer samples. For samples synthesized under higher benzenepressures we find a systematic degradation of the hydrogen absorption.

Hydrogen Absorption at Room Temperature in Nanoscale Titanium Benzene Complexes