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Nearly half a century ago, I joined an ambitious research project aimed atestablishing the mechanism of photodecomposition of ionic salts. We measuredthe mobilities and lifetimes of photoelectrons and photoholes in silver bromidein order to get an early-stage knowledge of the process. The last pairs ofquantities to study were the diffusion coefficients for which we got results,highly controversial at that time. Now we show that the diffusion data suggestthe formation of itinerant Jahn Teller small polarons as the next-stagephoto-carriers in silver halides.

Migration of photogenerated charge carriers in silver halides: small polaron transport