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The structural and electrical characterizations of mechanically-milled (MM)amorphous fast ionic conductors (a-FICs), viz. xAgI (100-x)[0.67 Ag\_2O-0.33V\_2O\_5] (x = 40, 50, 55 and 70) have been reported. The amorphisationis restricted only to the compositions which are well within the glass formingregion and all samples are found to be highly agglomerated and X-ray amorphousin nature. The frequency dependent ac conductivity, \sigma'(\omega), of theamorphous samples investigated in the frequency range 5Hz -13 MHz andtemperature range 100- 350 K shows a dc conductivity regime at low frequenciesand a dispersive regime at higher frequencies. The spectra can be described bythe Jonscher power law (JPL), \simga'(\omega) = \sigma\_dc +A(T) \omega\_n.However, the values \sigma\_dc (T) and A(T) both show two distinct Arrheniusregions and n (< 1) is found to be temperature dependent, i.e., decreasing withincreasing temperature.

Ion transport study of mechanically-milled amorphous AgI-Ag2O-V2O5 fast ionic conductors