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We propose a simple Monte Carlo method to calculate the interfacial freeenergy between the substrate and the material. Using this method we investigatethe interfacial free energys of the hard sphere fluid and solid phases near asmooth hard wall. According to the obtained interfacial free energys of thecoexisting fluid and solid phases and the Young equation we are able todetermine the contact angle with high accuracy, cos$\theta$ = 1:010(31), whichindicates that a smooth hard wall can be wetted completely by the hard spherecrystal at the interface between the wall and the hard sphere fluid.

Revisit of interfacial free energy of the hard sphere system near hard wall