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The folding transition of single, long semiflexible polymers was studied withspecial emphasis on the chain length effect using Monte Carlo simulations.While a relatively short chain (10-25 Kuhn segments) undergoes a large discretetransiton between swollen coil and compact toroid conformations, a long chain(50 Kuhn segments) exhibits an intrachain segregated state between thedisordered coil and ordered toroid.

Chain Length Dependence on Folding Transition of a Semiflexible Homo-polymer Chain: Appearance of a Core-Shell Structure