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Simulation studies are undertaken for the system Ag/Au(100) by means of grandcanonical Monte Carlo applied to a large lattice system. The interactions arecalculated using the embedded atom model. The formation of adsorbed Ag phasesof low dimensionality on Ag(100) is investigated and the influence of surfacedefects on the shape of the adsorption isotherms is studied. The results of thesimulations are discussed in the light of experimental information availablefrom electrochemical measurements.

Monte Carlo Simulation for the Formation and Growth of Low Dimensionality Phases During Underpotential Deposition of Ag on Au(100)