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Despite significant progress in synthesizing several new molecules and manypromising single device demonstrations, wide range acceptance of molecularelectronics as an alternative to CMOS technology has been stalled not only bycontroversial theories of a molecular device`s operation, for example theswitching mechanism, but also by our inability to reproducibly fabricate largearrays of devices. In this paper, we investigate the role of Casimir force asone of the potential source of a wide range of discrepancies in the reportedelectrical characteristics and high rate of device shorting in molecularelectronic switching junctions fabricated by sandwiching a molecular monolayerbetween a pair of planar metal electrode.

Impact of Casimir Force in Molecular Electronic Switching Junctions