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Feedstock and byproduct diffusion in the root growth of aligned CNT arrayswas discussed in this work. A non-dimensional modulus was proposed todifferentiate catalyst-decay controlled growth deceleration from diffusioncontrolled one. It was found that aligned MWNT arrays are usually free offeedstock diffusion while SWNT arrays are usually facing strong diffusionlimit. The present method can also be utilized to predict the maximum lengththat CNT forest can grow in certain CVD process.

Decelerating Growth of Vertically Aligned Carbon Nanotube Arrays: Kinetic Controlled or Diffusion Controlled?