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This paper describes how automatically generated detailed kinetic mechanismsare obtained for the oxidation of alkanes and how these models could lead to abetter understanding of autoignition and cool flame risks at elevatedconditions. Examples of prediction of the occurrence of different autoignitionphenomena, such as cool flames or two-stage ignitions are presented dependingon the condition of pressure, temperature and mixture composition. Threecompounds are treated, a light alkane, propane, and two heavier ones, n-heptaneand n-decane.

Use of detailed kinetic mechanisms for the prediction of autoignitions