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The prediction of auto-ignition delay times in HCCI engines has riseninterest on detailed chemical models. This paper described a validated kineticmechanism for the oxidation of a model Diesel fuel (n-decane and&#945;-methylnaphthalene). The 3D model for the description of low and hightemperature auto-ignition in engines is presented. The behavior of the modelfuel is compared with that of n-heptane. Simulations show that the 3D modelcoupled with the kinetic mechanism can reproduce experimental HCCI and Dieselengine results and that the correct modeling of auto-ignition in the cool flameregion is essential in HCCI conditions.

Kinetic modelling of a surrogate diesel fuel applied to 3D auto-ignition in HCCI engines