Open AccessNITRATO ADDUCTS AND DERIVATIVES: SYNTHESIS AND INFRARED STUDY
Author(s) -
Mouhamadou Birame Diop,
Libasse Diop
Publication year - 2017
Publication title -
journal of engineering studies and research
Language(s) - English
Resource type - Journals
eISSN - 2344-4932
pISSN - 2068-7559
DOI - 10.29081/jesr.v23i1.86
Subject(s) - denticity , adduct , octahedron , chemistry , trigonal bipyramidal molecular geometry , infrared spectroscopy , hydrogen bond , infrared , ligand (biochemistry) , supramolecular chemistry , crystallography , tin , stereochemistry , molecule , crystal structure , organic chemistry , physics , receptor , biochemistry , optics
Five new nitrato adducts and derivatives have been synthesized and studied by infrared spectroscopy. The suggested structures are discrete or of infinite chain type, the nitrate behaving as a bidentate or a monodentate ligand, the environment around the tin (IV) centres being octahedral or trigonal bipyramidal. When extra hydrogen bonds are considered supramolecular architectures may be obtained.