Synthesis and characterization of palladium(II) complexes with glycine coumarin derivatives
Author(s) -
Danijela Lj. Stojković,
Alessia Bacchi,
Davide Capucci,
Milica R. Milenković,
Božidar Čobeljić,
Srećko R. Trifunović,
Katarina Andjelković,
Verica V. Jevtić,
Nenad L. Vuković,
Milena Vukić,
Dušan Sladić
Publication year - 2016
Publication title -
journal of the serbian chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.227
H-Index - 45
eISSN - 1820-7421
pISSN - 0352-5139
DOI - 10.2298/jsc160915087s
Subject(s) - palladium , chemistry , dimethylamine , elemental analysis , proton nmr , infrared spectroscopy , nuclear magnetic resonance spectroscopy , hydrolysis , ligand (biochemistry) , recrystallization (geology) , coumarin , carbon 13 nmr , nuclear chemistry , spectroscopy , medicinal chemistry , organic chemistry , catalysis , paleontology , biochemistry , physics , receptor , quantum mechanics , biology
A Pd(II) complex with methyl 2-((1-(2,4-dioxochroman-3-ylidene)ethyl)amino)acetate was synthesized. The structures of both the ligand and Pd(II) complex were determined by elemental analysis, IR and NMR spectroscopy. Recrystallization of Pd(II) complex from DMF/water solution resulted in its hydrolysis and formation of dimethylamine-(2-((1-(2,4-dioxochroman-3-ylidene)ethyl)amino)acetato)palladium(II) complex, the structure of which was determined by elemental analysis, IR, 1H and 13C NMR spectroscopy, as well as X-ray analysis. [Projekat Ministarstva nauke Republike Srbije, br. OI 172055 i br. OI 172016
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