Open AccessКриоспектроскопическое исследование резонансных мультиплетов ν-=SUB=-s-=/SUB=- ~2ν-=SUB=-b-=/SUB=- в молекуле CHF-=SUB=-3-=/SUB=-
Author(s) -
С.М. Меликова,
K. S. Rutkovskiǐ,
D. N. Shchepkin,
С. Махолл,
В. Херребут
Publication year - 2021
Publication title -
optika i spektroskopiâ
Language(s) - English
Resource type - Journals
eISSN - 2782-6694
pISSN - 0030-4034
DOI - 10.21883/os.2021.08.51197.2002-21
Subject(s) - fermi resonance , anharmonicity , krypton , physics , atomic physics , resonance (particle physics) , fermi gamma ray space telescope , quantum number , excitation , spectrum (functional analysis) , infrared , chemistry , quantum mechanics , argon
The sequences of Fermi resonances vs~2vb in the IR spectrum of a solution of fluoroform (CHF3) in liquefied krypton are investigated. Here vs is the CH stretching vibration, vb is the bending vibration. It is shown that for a correct description of resonance multiplets (polyads) at a high degree of vibrational excitation, it is necessary to use an extended set of spectroscopic parameters. In particular, it is necessary to take into account the dependence of the anharmonic interaction constant asbb on the vibrational quantum numbers. The conclusions are generalized for the arbitrary case of the CH-chromophore CHX3.