Open AccessО возможностях многомерной эквидистантной абсорбционной спектроскопии в широком диапазоне частот в исследованиях фракций термической разгонки нефти
Author(s) -
Н Ю Егорова,
И.О. Конюшенко,
В. М. Немец,
С.А. Пеганов
Publication year - 2020
Publication title -
žurnal tehničeskoj fiziki
Language(s) - English
Resource type - Journals
eISSN - 1726-748X
pISSN - 0044-4642
DOI - 10.21883/os.2020.04.49208.309-19
Subject(s) - vacuum distillation , distillation , analytical chemistry (journal) , infrared spectroscopy , absorption spectroscopy , spectral line , spectroscopy , absorption (acoustics) , chemistry , resolution (logic) , equidistant , thermal , range (aeronautics) , materials science , optics , chromatography , thermodynamics , organic chemistry , physics , mathematics , computer science , geometry , quantum mechanics , astronomy , artificial intelligence , composite material
The features and possibilities of absorption molecular spectroscopy of complex mixtures of organic compounds by the instance of oil thermal distillation fractions are studied. The problem of studying the spectra of oil fractions as a single object of complex molecular composition was directly solved (i.e. without studing of molecular composition). Thereby multidimensional equidistant spectra were studied in a wide spectral range. Measurement conditions: frequency range from 500 to 1500 cm-1, spectral resolution 1 cm-1, frequency increment 0.5 cm-1, Objects under investigation - 33 fractions of thermal oil distillation. Results processing of spectroscopic measurements was carried out using methods of multifactor mathematical statistics. The efficiency of using absorption molecular spectroscopy in the far infrared region in the study and control of the optical characteristics (absorption spectra) of oil thermal distillation fractions is shown.