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Особенности формирования пентагональных микрокристаллов никеля в сплошных электроосажденных покрытиях при избирательном ингибировании роста их отдельных граней
Author(s) -
Н.С. Матвеева,
Н.Н. Грызунова,
И.С. Ясников
Publication year - 2021
Publication title -
fizika tverdogo tela
Language(s) - English
Resource type - Journals
eISSN - 1726-7498
pISSN - 0367-3294
DOI - 10.21883/ftt.2021.12.51681.168
Subject(s) - disclination , materials science , crystallography , nickel , coating , chemical engineering , nanotechnology , metallurgy , chemistry , liquid crystal , optoelectronics , engineering
The paper presents experimental facts indicating the possibility of controlling the habitus of microcrystals, which are structural units of electrodeposited nickel coatings. The introduction of additives (inhibitors) into the electrolyte of a certain chemical composition affects on the evolution of individual crystallographic facets of growing microcrystals and initiates the growth of microcrystal facets with a certain crystallographic orientation. This leads to the production of a nickel coating mainly consisting of microcrystals containing disclination-type defects and exhibiting pentagonal symmetry.

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