Open AccessAzoligands as Bridged in Macrocyclic Dinickel Complexes
Author(s) -
Vasile Lozan
Publication year - 2010
Publication title -
chemistry journal of moldova
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.275
H-Index - 5
eISSN - 2345-1688
pISSN - 1857-1727
DOI - 10.19261/cjm.2010.05(1).01
Subject(s) - chemistry , coordination complex , crystallography , transition metal , stereochemistry , metal , organic chemistry , catalysis
The coordination chemistry of dinickel macrocyclic hexaamine-dithiophenolate complexes of Robson-type with azoligands is presented in this microreview. All complexes have been characterised by IR-,UV/Visspectroscopy, and X-ray crystallography. The bioctahedral transition metal complexes of the type [(L6)Ni2(μ-L')]+ exhibit a rich coordination chemistry since the active coordination site L' is accessible for a wide range of exogenous coligands.