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The relationship between electron transfer rate and molecular conduction 2. The sequential hopping case
Author(s) -
Nitzan Abraham
Publication year - 2003
Publication title -
israel journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.908
H-Index - 54
eISSN - 1869-5868
pISSN - 0021-2148
DOI - 10.1560/ylbd-yf7y-4j4e-epqe
Subject(s) - chemistry , quantum tunnelling , thermal conduction , electron transfer , electron , limit (mathematics) , transfer (computing) , statistical physics , chemical physics , zero temperature , zero (linguistics) , condensed matter physics , quantum mechanics , physics , mathematical analysis , linguistics , philosophy , mathematics , parallel computing , computer science
This note discusses the relationship between a given bridge‐assisted electron transfer rate and the corresponding zero‐bias molecular conduction of the same molecular species, in the limit where both processes occur by sequential hopping. It follows a previous publication (A. Nitzan, J. Phys. Chem. A 2001 , 105 , 2677‐2679) in which the same issue was discussed for coherent tunneling transfer.