English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

The syntheses of tetranuclear complexes Mo,W 2 S 4 L 6  3 and Mo 2 Co 2 S 4 L 2 (CO) 2 (CH 3 CN) 2  4 (L = R 2 PS 2 ⁻; a: R = Et, b: R = Pr) containing the cubane-type Mo 2 M 2 S 4  core are reported. While in 4 both Mo atoms are chelated by L, the dithiophosphinato group acts as a chelating and bridging ligand in 3. It is shown that there exist four isomers of 3 which differ not only in the function of L but also in the kind of metals which are chelated and bridged. Magnetic and NMR spectroscopic data are given. The structure of a mixed crystal of the two β-isomers of 3a containing three bridging and three chelating ligands L is reported: orthorhombic space group Pbca, Z = 8, and lattice parameters a = 2186.6(7), b = 2264.0(7), and c = 2386.7(6) pm.

Clusterdithiophosphinate mit kubanartigem Mo 2 M 2 S 4 -Kern (M = Co, W) / Clusterdithiophosphinates with Cubane-Type Mo 2 M 2 S 4 -Core (M = Co, W)